If you are an Alice Mail user, today known primarily as TIM Mail, you have probably wondered how to integrate or use Certified Electronic Mail (PEC). In an increasingly digitized world, PEC has become an almost indispensable tool, not only for professionals and companies but also for private citizens who wish to communicate with the Public Administration or send documents with legal value.
But how exactly does PEC work with an Alice/TIM Mail account? Is it possible to get one directly from TIM, or do you need to look elsewhere? And, above all, how do you configure and use it effectively?
I am here to guide you step by step. In this article, we will explore everything there is to know about PEC for Alice Mail users. From its legal importance to available options, through to practical configuration on webmail, email clients, and smartphones. Get ready to discover how to add the power and security of PEC to your digital world, without stress and with the right awareness.
What is PEC and Why is it So Important?
Before diving into technical details, let’s do a quick review. Certified Electronic Mail (PEC) is an email system that gives email messages the same legal value as a registered letter with return receipt. This is possible thanks to a system of receipts that certify:
- Sending: The sender’s PEC provider sends an acceptance receipt.
- Delivery: The recipient’s PEC provider sends a delivery (or non-delivery) receipt.
These receipts, digitally signed by the providers, attest not only to the sending and receiving but also to the date, time, and integrity of the message content and any attachments.
Why is it important?
- Official Communications: It is the tool of choice for communicating with public bodies, participating in competitions, sending cancellations, invoices, and important documents.
- Legal Value: It replaces the registered letter with return receipt, offering savings in time and money.
- Security and Certainty: It guarantees the identity of the sender and the recipient (if both use PEC) and the integrity of the message.
- Mandatory Status: It is mandatory for companies, professionals registered with orders, and sole proprietorships. Even for private individuals, it is becoming increasingly useful and, in some contexts, necessary.
Understanding PEC is the first step to making the most of it, even if your starting point is an Alice Mail account.
Does Alice/TIM Mail Offer a Dedicated PEC?
This is one of the most frequently asked questions. The answer is: yes, TIM offers a PEC service, known as TIM PEC.
This is a paid service, separate from the normal @alice.it or @tim.it mailbox, which provides a certified email address like username@timpec.it.
Main Features of TIM PEC (indicative, always check the TIM website):
- Cost: Usually involves an annual fee. TIM may offer promotions or packages, especially for business customers.
- Storage: Offers dedicated storage space, often with the possibility to expand it for a fee.
- Security: Includes antivirus and antispam systems.
- Legal Archiving: May include or offer as an option a compliant preservation service for PEC messages, important for maintaining legal value over time.
- Access: Accessible via dedicated webmail or configurable on email clients and mobile devices.
How to Activate It?
Generally, activation takes place via the official TIM website. You will need to provide your personal data and an identity document for identification, as required by PEC regulations.
Pros and Cons:
- Pro: Having a single provider (TIM) for connectivity and PEC can simplify management.
- Con: It might not be the cheapest solution on the market, and it is important to compare offers from other certified providers.
If TIM offers PEC, why consider an external provider? The answer often lies in flexibility, costs, and specific features offered by other managers.
Configuring an External PEC on Alice/TIM Mail

Many users already own a PEC purchased from other providers (such as Aruba, Poste Italiane, Namirial, Register.it, etc.) or prefer to choose one for cost or functionality reasons. The good news is that, although it is not possible to transform an @alice.it address into a PEC, it is possible to manage an external PEC via the TIM Mail interface or configure it on a client alongside your Alice account.
Why Use an External PEC?
- Costs: Specialized providers often offer very competitive PEC packages.
- Additional Features: Some offer unlimited space, SMS notifications, advanced archiving, etc.
- Independence: Keeping the PEC separate from the connectivity provider can be useful in case of changing operators.
Let’s see how to configure it.
Configuration via TIM Webmail
The current TIM webmail (which replaced the old Alice webmail) generally allows adding external accounts. However, this function is designed primarily for standard email accounts and may have limitations with PEC, especially regarding “certified” sending and receipt management.
The typical procedure (always verify on TIM webmail) is:
- Log in to your TIM webmail.
- Look for Settings (often a gear icon).
- Find the Account or Manage Accounts section.
- Look for the Add email account option.
- Enter the PEC address and password.
- Here is the critical point: If the webmail does not recognize the PEC parameters automatically, you will have to enter them manually. IT IS FUNDAMENTAL to use the IMAP/POP3 and SMTP parameters provided by your PEC provider, not those of Alice/TIM.
Warning: Managing PEC via TIM webmail (as an added account) might not guarantee the full legal value of the transmission and optimal receipt management. It is often advisable to use your PEC provider’s webmail or a dedicated email client.
Configuration on Email Clients (Outlook, Thunderbird, Apple Mail)
This is the most recommended and flexible method to manage both Alice Mail and your PEC in the same place. It allows you to have full control and use all PEC features.
The general procedure is:
- Open your email client (Outlook, Thunderbird, Apple Mail, etc.).
- Go to File > Add Account (or similar procedure).
- Choose the option for manual configuration or “Other account”.
- Enter your name, PEC address, and password.
- Enter the PEC server parameters:
- Account Type: Choose IMAP (recommended for synchronizing emails across multiple devices) or POP3.
- Incoming Mail Server (IMAP/POP3): Enter the address provided by your PEC provider (e.g.,
imaps.pec.aruba.it,mail.postecert.it). DO NOT usein.alice.it! - Outgoing Mail Server (SMTP): Enter the address provided by your PEC provider (e.g.,
smtps.pec.aruba.it,relay.postecert.it). DO NOT useout.alice.it! - Ports and Security: Use the ports and encryption methods (SSL/TLS) specified by your PEC provider. These are different from standard ones and crucial for operation.
- Authentication: Ensure that the SMTP server requires authentication, using the same credentials as the incoming mail.
Once configured, you will see your PEC mailbox as a separate account next to your Alice Mail account in your client.
Configuration on Smartphone (iOS/Android)
The procedure is very similar to that for desktop clients:
- Go to the Settings of your smartphone.
- Select Mail (iOS) or Accounts (Android).
- Choose Add Account.
- Select Other (or the option for manual configuration).
- Enter your details (name, PEC address, password).
- Manually enter the IMAP/POP3 and SMTP parameters of your PEC provider, as described in the previous section, paying close attention to servers, ports, and security.
Alternatively, many PEC providers offer dedicated apps that simplify configuration and use of PEC on mobile.
Using PEC with Alice/TIM Mail: Best Practices
Once the PEC is configured, how do you use it best, especially if you manage it alongside Alice?
- Clear Separation: Use PEC only for communications requiring legal value or certainty of delivery. For informal emails, continue using your Alice/TIM account.
- Attention to Sending: When writing a new email from a client, make sure to select the PEC address as the sender if you are sending a certified communication.
- Receipt Management: Always keep acceptance and delivery receipts. They are the legal proof. Most clients save them automatically, but it is good to create dedicated folders.
- Archiving: Remember that PEC has limited space. Periodically archive or download important messages, especially if your provider does not offer a long-term preservation service.
- Security: Protect your PEC password as you would your bank account password. Consider using complex passwords and, if available, two-factor authentication. If you are concerned about scams, learn about reliable online loans and anti-scam guides, as the same security logic applies to email management.
- Support: For specific problems with PEC (non-delivery, errors), contact your PEC provider’s support. If you are looking for a provider and need support, you can contact Namirial for fast assistance, as they are one of the main providers.
Troubleshooting Common Problems
- Not Sending/Receiving: 99% of the time the cause is incorrect server parameters (IMAP/POP3/SMTP). Check them meticulously on your PEC provider’s website. Ensure that ports and encryption (SSL/TLS) are correct.
- Authentication Error: Incorrect password or, more often, SMTP authentication is not enabled or configured correctly.
- Missing Receipts: Check the spam folder or verify your PEC provider’s settings.
- Error Message from Recipient: Their PEC mailbox might be full, or the address might be incorrect. The non-delivery receipt will give you indications.
- Choose and activate your PEC mailbox
You can activate the TIM PEC service directly from the official website or choose an external provider like Aruba or Namirial for different costs and functions.
- Retrieve IMAP and SMTP parameters
It is fundamental to obtain the specific configuration parameters of your PEC provider. Never use the in.alice.it or out.alice.it servers for PEC.
- Configure PEC on PC Client
Open Outlook or Thunderbird, add a new account, and manually enter the PEC servers, ports, and SSL/TLS encryption provided by the manager.
- Set up PEC on Smartphone
Go to the phone’s Mail settings, add an ‘Other’ account by entering the correct server parameters, or download the provider’s dedicated app.
- Send certified messages
When writing a new email from the client, select the PEC address as the sender to ensure the message has full legal value.
- Archive legal receipts
Carefully keep the acceptance and delivery receipts you receive after sending: they constitute the legal proof of communication enforceable against third parties.
In Brief (TL;DR)
PEC offers legal value to your email communications, equating them to a registered letter with return receipt.
TIM offers its own PEC service (@timpec.it), but you can use any external PEC provider.
The best method to manage Alice Mail and PEC together is to use an email client (Outlook, Thunderbird, Mail) or dedicated apps, configuring the PEC with its specific parameters (IMAP/SMTP).
Conclusions

Integrating Certified Electronic Mail into one’s digital workflow is no longer an option, but a necessity for multiple aspects of professional and private life. For long-time users of Alice Mail, today TIM Mail, understanding how to make this tool coexist or integrate is fundamental. Although TIM offers its own PEC solution, the flexibility of the market allows choosing from numerous providers, each with its own strengths.
The key to success lies in correct configuration. The most common mistake is trying to use Alice/TIM parameters for PEC: it is essential to understand that PEC, even if managed by the same client, is a technically separate service, with its own servers, ports, and security protocols. Ignoring this detail inevitably leads to frustration and malfunctions.
The most robust and recommended approach is the use of a desktop or mobile email client. These applications offer the necessary flexibility to manage multiple accounts, including PEC ones, guaranteeing full control over features, certified sending, and meticulous management of receipts, which constitute the heart of the legal value of PEC. Management via TIM webmail, while possible for reading, presents significant limits for certified use.
Adopting PEC means embracing a way of communicating that is more secure, traceable, and legally valid. It means being able to interact with the Public Administration, cancel contracts, and send important documents with the certainty of receipt, saving time and money compared to traditional methods. For an Alice/TIM user, this does not require abandoning their historic address, but supplementing it with a powerful and specific tool, learning to use it with awareness and the right technical configuration.
Frequently Asked Questions

No, it is not possible. The @alice.it or @tim.it address is a standard email account. You must purchase a separate PEC service, which will have a specific domain (e.g., @timpec.it, @pec.it, @legalmail.it, etc.).
There are no universal parameters. Each PEC provider (Aruba, Poste, Namirial, TIM PEC, etc.) has its own specific parameters (server addresses, ports, security methods). You must mandatorily obtain them from your PEC provider’s website or support.
Costs vary greatly depending on the provider and the chosen package (space, notifications, archiving). Generally, it starts from a few euros per year for basic solutions, up to tens or hundreds of euros for professional solutions with compliant archiving.
Yes, absolutely. You can configure it in your phone’s default mail app (iOS or Android) using the correct parameters, or use the dedicated app provided by your PEC provider, if available.
Yes, provided it is configured correctly with your PEC provider’s parameters and you send the message using the PEC account as the sender. The legal value comes from the management system and the receipts, not from the application you use to send.




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